Single Bonds & Lewis Structures
For each molecule:
Remember: Bonds needed = 8 - valence electrons (except H, which needs only 2)
Problem 1: Methane (CH4)
Draw the Lewis structure for methane.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| C | 1 | ______ | ______ | ______ |
| H | 4 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 2: Water (H2O)
Draw the Lewis structure for water.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| H | 2 | ______ | ______ | ______ |
| O | 1 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 3: Ammonia (NH3)
Draw the Lewis structure for ammonia.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| N | 1 | ______ | ______ | ______ |
| H | 3 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 4: Hydrogen Fluoride (HF)
Draw the Lewis structure for hydrogen fluoride.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| H | 1 | ______ | ______ | ______ |
| F | 1 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 5: Hydrogen Sulfide (H2S)
Draw the Lewis structure for hydrogen sulfide.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| H | 2 | ______ | ______ | ______ |
| S | 1 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 6: Methanol (CH3OH)
Draw the Lewis structure for methanol (wood alcohol).
Hint: Carbon is bonded to 3 hydrogens and 1 oxygen. The oxygen is bonded to 1 hydrogen.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| C | 1 | ______ | ______ | ______ |
| H | 4 | ______ | ______ | ______ |
| O | 1 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ + ______ = ______
Problem 7: Methylamine (CH3NH2)
Draw the Lewis structure for methylamine.
Hint: Carbon is bonded to 3 hydrogens and 1 nitrogen. The nitrogen is bonded to 2 hydrogens.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| C | 1 | ______ | ______ | ______ |
| H | 5 | ______ | ______ | ______ |
| N | 1 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ + ______ = ______
Problem 8: Ethane (C2H6)
Draw the Lewis structure for ethane (two carbons bonded together).
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| C | 2 | ______ | ______ | ______ |
| H | 6 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 9: Chloromethane (CH3Cl)
Draw the Lewis structure for chloromethane.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| C | 1 | ______ | ______ | ______ |
| H | 3 | ______ | ______ | ______ |
| Cl | 1 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ + ______ = ______
Problem 10: Dichloromethane (CH2Cl2)
Draw the Lewis structure for dichloromethane.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| C | 1 | ______ | ______ | ______ |
| H | 2 | ______ | ______ | ______ |
| Cl | 2 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ + ______ = ______
Problem 11: Phosphine (PH3)
Draw the Lewis structure for phosphine.
Hint: Phosphorus behaves like nitrogen!
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| P | 1 | ______ | ______ | ______ |
| H | 3 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 12: Nitrogen Trifluoride (NF3)
Draw the Lewis structure for nitrogen trifluoride.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| N | 1 | ______ | ______ | ______ |
| F | 3 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 13: Oxygen Difluoride (OF2)
Draw the Lewis structure for oxygen difluoride.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| O | 1 | ______ | ______ | ______ |
| F | 2 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 14: Silicon Tetrafluoride (SiF4)
Draw the Lewis structure for silicon tetrafluoride.
Hint: Silicon behaves like carbon!
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| Si | 1 | ______ | ______ | ______ |
| F | 4 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 15: Ethanol (C2H5OH)
Draw the Lewis structure for ethanol (drinking alcohol).
Hint: Two carbons bonded together; one carbon has 3 H's, the other has 2 H's and is bonded to an OH group.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| C | 2 | ______ | ______ | ______ |
| H | 6 | ______ | ______ | ______ |
| O | 1 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ + ______ = ______
Problem 16: Hydrogen Peroxide (H2O2)
Draw the Lewis structure for hydrogen peroxide.
Hint: The two oxygens are bonded to each other, and each oxygen is also bonded to one hydrogen.
| Atom | How many? | Valence e⁻ each | Total from this atom | Bonds needed (each) |
|---|---|---|---|---|
| H | 2 | ______ | ______ | ______ |
| O | 2 | ______ | ______ | ______ |
Total valence electrons: ______ + ______ = ______
Problem 17
What is the difference between an ionic bond and a covalent bond?
Problem 18
Why does carbon typically form 4 bonds while oxygen typically forms 2 bonds? Use valence electrons in your explanation.
Problem 19
What is electronegativity? Explain it in your own words.
Problem 20: Isomers
What are isomers? Explain in your own words.
Problem 21: Isomers of C2H6O
The molecular formula C2H6O has two different isomers. Draw the Lewis structure for BOTH isomers.
Hint: In one isomer, the oxygen is at the end of the chain (alcohol). In the other, the oxygen is in the middle (ether).
Isomer 1: Ethanol (CH3CH2OH)
Oxygen at the END
Isomer 2: Dimethyl Ether (CH3OCH3)
Oxygen in the MIDDLE
Problem 22
Complete the table below:
| Molecule | Total Valence e⁻ | # Single Bonds | # Lone Pairs (total) |
|---|---|---|---|
| H2O | |||
| CH4 | |||
| NH3 | |||
| HF | |||
| H2S |