Master the Strategy for Chemistry Calculations
This study guide breaks down percentage word problems into manageable steps. Each problem type includes a complete walkthrough with strategic questions to ask yourself. Practice identifying the patterns, and soon you'll solve these problems automatically!
Ask yourself these questions EVERY time:
Example: A quarter from 1964 is made of 90% silver and has a mass of 5.670 g. What is the mass of silver in the quarter?
1Identify the WHOLE
The WHOLE is the total mass of the quarter = 5.670 g
Ask: "What does 100% represent here?" → The entire quarter
2Identify the PART
The PART is what we're finding = mass of silver
Ask: "What portion am I calculating?" → The silver portion
3Convert percentage to decimal
\[90\% = \frac{90}{100} = 0.90\]
4Calculate: Part = Decimal × Whole
\[\text{Mass of silver} = 0.90 \times 5.670 \text{ g} = 5.10 \text{ g}\]
Practice Template for Type 1:
The WHOLE (100%) = __________
The PART (what I'm finding) = __________
Percentage as decimal = __________
Calculation: __________ × __________ = __________
Example: If silver is worth $31.02 per troy ounce, and there are 31.1 g in 1 troy ounce, what is the value of silver in all 1964 quarters ever minted (1,950,000,000 quarters)?
1Break into sub-problems
Sub-problem A: Total mass of silver in all quarters
Sub-problem B: Convert grams to troy ounces
Sub-problem C: Calculate dollar value
2Solve Sub-problem A: Total silver mass
From Type 1, we know each quarter has 5.10 g of silver
\[\text{Total silver} = 5.10 \text{ g/quarter} \times 1,950,000,000 \text{ quarters}\]
\[= 9,945,000,000 \text{ g} = 9.945 \times 10^9 \text{ g}\]
3Solve Sub-problem B: Convert to troy ounces
\[9.945 \times 10^9 \cancel{\text{ g}} \times \frac{1 \text{ troy oz}}{31.1 \cancel{\text{ g}}} = 3.20 \times 10^8 \text{ troy oz}\]
4Solve Sub-problem C: Calculate value
\[3.20 \times 10^8 \cancel{\text{ troy oz}} \times \frac{\$31.02}{1 \cancel{\text{ troy oz}}} = \$9.93 \times 10^9\]
Final Answer: $9.93 billion
Common Mistake: Jumping to the end!
Multi-step problems require patience. Write down each intermediate answer. Don't try to do it all in one calculation!
Example: The atmosphere is 20.95% oxygen. If you breathe 0.5 L of air, what volume of oxygen did you breathe?
1Identify the WHOLE
The WHOLE is the total volume of air = 0.5 L
Ask: "What does 100% represent?" → All the air breathed
2Identify the PART
The PART is what we're finding = volume of oxygen
3Convert percentage to decimal
\[20.95\% = \frac{20.95}{100} = 0.2095\]
4Calculate: Part = Decimal × Whole
\[\text{Volume of O}_2 = 0.2095 \times 0.5 \text{ L} = 0.10 \text{ L}\]
Key Insight:
Type 3 problems are structurally identical to Type 1 - just with different units! The strategy doesn't change. Mass, volume, number of atoms - the math is the same.
Example: Your body contains about 16 kg of carbon, and 18% of that carbon is carbon-12. If you have \(3.0 \times 10^{27}\) carbon atoms total, how many are carbon-12?
1Identify the WHOLE
The WHOLE is the total carbon atoms = \(3.0 \times 10^{27}\) atoms
Note: The 16 kg is extra information - we already have the atom count!
2Identify the PART
The PART is what we're finding = number of C-12 atoms
3Convert percentage to decimal
\[18\% = \frac{18}{100} = 0.18\]
4Calculate: Part = Decimal × Whole
\[\text{C-12 atoms} = 0.18 \times 3.0 \times 10^{27} = 5.4 \times 10^{26} \text{ atoms}\]
Watch Out: Red Herring Information!
Some problems give you extra information you don't need. The 16 kg of carbon was a distraction - we already had the atom count. Always ask: "What information do I actually need for this calculation?"
Use this flowchart to decide your approach:
Question 1: Is this a one-step or multi-step problem?
Question 2: What does 100% represent?
Question 3: Am I given unnecessary information?
| Percentage | Decimal | Example Calculation |
|---|---|---|
| 100% | 1.00 | 100% of 50 g = 1.00 × 50 g = 50 g |
| 90% | 0.90 | 90% of 5.670 g = 0.90 × 5.670 g = 5.10 g |
| 50% | 0.50 | 50% of 100 atoms = 0.50 × 100 = 50 atoms |
| 20.95% | 0.2095 | 20.95% of 0.5 L = 0.2095 × 0.5 L = 0.10475 L |
| 18% | 0.18 | 18% of 3.0 × 10²⁷ = 0.18 × 3.0 × 10²⁷ = 5.4 × 10²⁶ |
| 10% | 0.10 | 10% of 200 mL = 0.10 × 200 mL = 20 mL |
| 5% | 0.05 | 5% of 1000 g = 0.05 × 1000 g = 50 g |
| 1% | 0.01 | 1% of 250 atoms = 0.01 × 250 = 2.5 atoms |
Make sure you can answer YES to all of these: