Periodic Table Organization

Understanding the Map of Elements

Why the Periodic Table is Organized This Way

The periodic table isn't random - it's organized by electron configuration! Elements in the same column (group) have similar properties because they have the same number of valence electrons.

Key Terms
  • Period: A horizontal row (1-7). Period number = highest energy level being filled.
  • Group: A vertical column (1-18). Elements in the same group have similar properties.
  • Block: A region of the periodic table based on which sublevel is being filled (s, p, d, or f).

1. The Four Blocks of the Periodic Table

The periodic table is divided into four blocks based on which sublevel is being filled:

s-Block

Groups 1-2 (plus H and He)

Filling: ns¹ or ns²

Includes: Alkali metals, Alkaline earth metals

p-Block

Groups 13-18

Filling: np¹ through np⁶

Includes: Halogens, Noble gases, many nonmetals

d-Block

Groups 3-12

Filling: (n-1)d¹ through (n-1)d¹⁰

Includes: Transition metals

f-Block

Bottom two rows

Filling: (n-2)f¹ through (n-2)f¹⁴

Includes: Lanthanides (4f), Actinides (5f)

Quick Reference:
  • s-block: 2 columns on the LEFT
  • p-block: 6 columns on the RIGHT
  • d-block: 10 columns in the MIDDLE
  • f-block: 14 columns at the BOTTOM

Example 1: Identifying Blocks

Problem: Groups 13-18 form the area where which electron sublevels are being filled?

Solution: Groups 13-18 are the p-block, so p sublevels are being filled.

(Note: The s electrons are already filled before the p sublevel starts)

2. Important Element Families

Alkali Metals (Group 1)

Elements: Li, Na, K, Rb, Cs, Fr

Valence: ns¹ (1 valence electron)

Typical Ion: +1 (loses 1 e⁻)

Properties: Very reactive metals, soft, low density

Alkaline Earth Metals (Group 2)

Elements: Be, Mg, Ca, Sr, Ba, Ra

Valence: ns² (2 valence electrons)

Typical Ion: +2 (loses 2 e⁻)

Properties: Reactive metals, harder than Group 1

Halogens (Group 17)

Elements: F, Cl, Br, I, At

Valence: ns²np⁵ (7 valence electrons)

Typical Ion: -1 (gains 1 e⁻)

Properties: Very reactive nonmetals

Noble Gases (Group 18)

Elements: He, Ne, Ar, Kr, Xe, Rn

Valence: ns²np⁶ (8 valence, full outer shell)

Typical Ion: 0 (rarely form ions)

Properties: Extremely unreactive, colorless gases

Transition Metals (Groups 3-12)

Examples: Fe, Cu, Zn, Ag, Au, Pt

Filling: d sublevels

Properties: Can form multiple ions (Fe²⁺ and Fe³⁺), often colored compounds, good conductors

Example 2: Group Identification

Problem: Which group contains the alkali metals?

Answer: Group 1

Note: Hydrogen is in Group 1 but is NOT an alkali metal - it's a nonmetal!

Example 3: Noble Gas Identification

Problem: Which element is NOT a noble gas: Ra, Xe, He, or Ar?

Answer: Ra (Radium)

Ra is in Group 2 (alkaline earth metals). Noble gases are in Group 18.

Common Confusion: Don't confuse Ra (Radium - Group 2) with Rn (Radon - Group 18, noble gas). They sound similar but are very different!

3. Metals, Nonmetals, and Metalloids

The Three Categories
Metals (Left side)
  • Shiny (lustrous)
  • Good conductors
  • Malleable & ductile
  • LOSE electrons
  • Form cations (+)
Nonmetals (Right side)
  • Dull (not shiny)
  • Poor conductors
  • Brittle
  • GAIN electrons
  • Form anions (-)
Metalloids (Staircase)
  • B, Si, Ge, As, Sb, Te
  • Properties of both
  • Semiconductors
  • Used in electronics
Finding Metalloids: Look for the "staircase" line on the periodic table that separates metals from nonmetals. Metalloids touch this line (except Al, which is a metal).

4. Periodic Trends

Properties of elements follow predictable patterns across the periodic table.

Atomic Radius

The size of an atom (distance from nucleus to outermost electrons)

← Decreases across period →

More protons pull electrons closer

↓ Increases down group ↓

More energy levels = bigger atom

Largest atoms: Bottom-left (Cs, Fr)

Smallest atoms: Top-right (He excluded, so F)

Example 4: Atomic Radius

Problem: In Group 15, which element has the smallest atomic radius?

Options: Bi, P, As, N

Solution: Atomic radius decreases going UP a group.

Order from largest to smallest: Bi > As > P > N

Answer: N (Nitrogen) - it's at the top of Group 15

Metallic Character

How "metal-like" an element is (shiny, conductive, loses electrons easily)

← Decreases across period →

Elements become more nonmetallic

↓ Increases down group ↓

Easier to lose electrons = more metallic

Most metallic: Bottom-left (Cs, Fr)

Least metallic: Top-right (F)

Example 5: Metallic Character

Problem: In Group 14, which element is the MOST metallic?

Options: C, Si, Ge, Sn

Solution: Metallic character increases going DOWN a group.

Answer: Sn (Tin) - it's at the bottom of the listed options

(Pb is even lower and more metallic, but wasn't an option)

Quick Trend Summary
Property Across Period (→) Down Group (↓)
Atomic Radius Decreases Increases
Metallic Character Decreases Increases
Ionization Energy Increases Decreases
Electronegativity Increases Decreases

5. Reactivity Patterns

Which Groups Are Most/Least Reactive?
Category Reactivity Why?
Noble Gases (18) LEAST reactive Full outer shell - stable!
Alkali Metals (1) VERY reactive Only 1 electron to lose
Halogens (17) VERY reactive Only 1 electron needed to fill shell

Example 6: Reactivity

Problem: Which group contains the LEAST reactive elements?

Options:

  • a. Alkali Metals
  • b. Halogens
  • c. Alkaline Earth Metals
  • d. Noble Gases

Answer: d. Noble Gases

Noble gases have full outer shells and rarely react with anything.

Quick Reference Summary

Key Facts to Remember
Group 1 Alkali Metals - 1 valence electron, +1 ion
Group 2 Alkaline Earth Metals - 2 valence electrons, +2 ion
Groups 3-12 Transition Metals - d-block, variable charges
Group 17 Halogens - 7 valence electrons, -1 ion
Group 18 Noble Gases - 8 valence electrons (2 for He), unreactive
Lanthanides/Actinides f-block - filling f sublevels
Common Test Questions:
  • "Which group contains..." - Know your group numbers!
  • "Which element is NOT a noble gas" - Watch for Ra vs Rn trap
  • "Most/least metallic" - Bottom-left is most metallic
  • "Smallest/largest atomic radius" - Top-right is smallest
  • "Least reactive" - Noble gases (Group 18)